Reactions of d0 alkylidene and amide complexes with silanes
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چکیده
منابع مشابه
Synthesis of Ru alkylidene complexes
The present work describes the robust synthesis of Ru alkylidene complexes (PCy(3))(2)Cl(2)Ru=CHR - precursors for metathesis catalysts. Moreover, the dynamic behavior of complexes where R = 2-naphthyl and 2-thienyl was studied. (1)H NMR techniques were employed to establish the preferred conformations in solution for both complexes and the energy barrier for rotation around single (Ru=)CH-C(th...
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Addition of 1 equiv of [HNMe2Ph]BAr4 (Ar ) 3,5-(CF3)2C6H3) to Mo(NAr)(CHCMe2Ph)(Pyrrolide)2 (Pyrrolide ) parent pyrrolide (Pyr) or 2,5-dimethylpyrrolide (Me2Pyr)) species in THF produced [Mo(NAr)(CHCMe2Ph)(Pyrrolide)(THF)x]BAr4 species (x ) 2 for Me2Pyr (1b) or 3 (1a) for Pyr; Ar ) 2,6-diisopropylphenyl). [Mo(NAr)(CHCMe2Ph)(Me2Pyr)(2,4-lutidine)]BAr4 (1c) was formed upon addition of 2,4-lutidin...
متن کاملHosomi-Sakurai reactions of silacyclic allyl silanes.
Substituted silacyclohexenes, generated through silene-diene [4 + 2] cycloaddition reactions, undergo Lewis acid promoted Sakurai type reactions with acetals to afford, following oxidation of the resultant fluorosilane, 1,4-diols with four contiguous chiral centres.
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Monoaryloxide-pyrrolide (MAP) olefin metathesis catalysts of molybdenum that contain a chiral bitetralin-based aryloxide ligand are efficient for ethenolysis of methyl oleate, cyclooctene, and cyclopentene. Ethenolysis of 5000 equiv of methyl oleate produced 1-decene (1D) and methyl-9-decenoate (M9D) with a selectivity of >99%, yields up to 95%, and a TON (turnover number) of 4750 in 15 h. Tung...
متن کاملOptimum synthesis of (chloromethyl)silanes by chlorination and methylation reactions of chloro(methyl)silanes
Comparative studies on chlorination and methylation reactions have been carried out to afford chloromethyl(methyl)silanes. For chlorination reactions, three types of initiators, viz., azobisisobutyronitrile, benzoyl peroxide and dicumyl peroxide have been studied at different reaction conditions, e.g., solvent, temperature, time duration of reaction and molar ratio of reactants in view to get o...
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ژورنال
عنوان ژورنال: Pure and Applied Chemistry
سال: 2001
ISSN: 1365-3075,0033-4545
DOI: 10.1351/pac200173020331